Simultaneous TG/DTG-DSC analysis – application in ceramic artefacts

Authors

  • Katerina Mihaylova
  • Bilyana Kostova
  • Irena Dimitrova

DOI:

https://doi.org/10.33919/ansd.22.7.6

Keywords:

simultaneous TG/DTG-DSC analysis, archaeological chemistry, ceramic

Abstract

The aim of this paper is to promote thermal analysis as a method for the study of archaeological ceramics. In order to achieve this goal, the nature of the thermal methods (thermal processes, types of thermal methods and their application) is described. Specific experimental measurements by simultaneous TG/DTG-DSC analysis of ceramic archaeological artifacts are also presented.

References

Atkins, P.W., T.L. Overton, J.P. Rourke, M.T. Weller, F.A. Armstrong, 2010. Shriver and Atkins Inorganic Chemistry. (5th ed.), W.H. Freeman and Company, 824.

Böke H., S. Akkurt, B. İpekoğlu, E. Uğurlu, 2006. Characteristics of brick used as aggregate in historic brick-lime mortars and plasters. Cem Concr Res, 36(6), 1115-1122. https://doi.org/10.1016/j.cemconres.2006.03.011

Brown, M. E., P. K. Gallacher (Eds.), 2003. Handbook of thermal analysis and calorimetry. Vol. 2. Applications to inorganic and miscellaneous materials. Elsevier, 905 pp.

Brown, M. E. (Ed.), 2004. Introduction to thermal analysis techniques and applications. Kluwer Academic Publishers. New York, Boston, Dordrecht, London, Moscow, 264 pp.

Cement Science. Buoyancy effect of TGA experiment, 2013. https://www.cementscience.com/2013/04/buoyancy-effect-of-tga-experiment.html, (April 30)

Dembicki, H. D., 2017. Practical petroleum geochemistry for exploration and production (A. S. Shapiro, Ed.). Elsevier Gezondheidszorg, 751 pp.

El Ouahabi M., L. Daoudi, F. Hatert, N. Fagel, 2015. Modified mineral phases during clay ceramic firing. Clays Clay Miner. 63, 404–413. https://doi.org/10.1346/CCMN.2015.0630506

Fakirov, S., 1990. Metodi na termichen analiz. [Thermal analysis methods]. University press “St. Kl. Ohridski”, Sofia, 262 pp.

Földvári M., 2011. Handbook of the thermogravimetric system of minerals and its use in geological practice. Occasional Papers of the Geological Institute of Hungary. Budapest. https://doi.org/10.1556/ceugeol.56.2013.4.6

Gabbott, P. (Ed.), 2008. Principles and applications of thermal analysis. Blackwell Publishing. Oxford, UK, 464 pp.

Goffer Z., 2007. Archaeological chemistry. Chemical analysis: A series of monographs on analytical chemistry and its applications, Wiley & Sons, Inc., 623 pp.

Hatakeyama T., Zk. Liu, 1998. Handbook of thermal analysis. Sussex, England, John Wiley & Sons Ltd., 452 pp.

Imman S., P. Khongchamnan, W. Wanmolee, N. Laosiripojana, T. Kreetachat, Ch. Akulthaew, Ch. Chokejaroenrat, N. Suriyachai, 2021. Fractionation and characterization of lignin from sugarcane bagasse using a sulfuric acid catalyzed solvothermal process. RSC Advances. 43(11). https://doi.org/10.1039/D1RA03237B

Kaushik, N., 2011. Difference between DSC and DTA. Difference between similar terms and objects. Retrieved from: http://www.differencebetween.net/science/difference-between-dsc-and-dta/, (July 29).

Moropoulou A, A. Bakolas, K. Bisbikou, 1995. Characterization of ancient, byzantine and later historic mortars by thermal and X-ray diffraction techniques. Thermochim. Acta. Vol. 269-270, 779-795. https://doi.org/10.1016/0040-6031(95)02571-5

Palanivel R., U. Rajesh Kumar, 2009. Thermal and spectroscopic analysis of ancient potteries. Romanian Journal of Physics. 56(1-2), 195-208.

Papadopoulou, D.N., M. Lalia-Kantouri, N. Kantiranis, J. A. Stratis, 2006. Thermal and mineralogical contribution to the ancient ceramics and natural clays characterization. J Therm Anal Calorim 84, 39–45. https://doi.org/10.1007/s10973-005-7173-y

Peacock D. P. S., 1970. The scientific analysis of ancient ceramics: a review. World Archaeology, 1(3)375-389.

Parlouer, P. P. Simultaneous TG-DSC, 1987. A new technique for thermal analysis. Thermochimica Acta, 121, 307–322.

Skotnicki, M., J. A. Aguilar, M. Pyda, P. Hodgkinson, 2015. Bisoprolol and bisoprolol-valsartan compatibility studied by differential scanning calorimetry, nuclear magnetic resonance and X-Ray powder diffractometry. Pharm Res 32, 414–429. https://doi.org/10.1007/s11095-014-1471-7

Speyer, R. F., 1994. Thermal analysis of materials. Marcel Dekker, INC., New York, 285 pp.

Velosa A.L., J. Coroado, M.R. Veiga, F. Rocha, 2007. Characterisation of roman mortars from Conímbriga with respect to their repair. Mater Charact. 58(11-12), 1208-1216. https://doi.org/10.1016/j.matchar.2007.06.017

West, A. W. 2014. Solid State Chemistry and its Applications (2nd ed.). John Wiley and Sons, 584 pp.

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Published

2022-12-30

How to Cite

Mihaylova, K., Kostova, B., & Dimitrova, I. (2022). Simultaneous TG/DTG-DSC analysis – application in ceramic artefacts. Annual of Natural Sciences Department, 7, 55–70. https://doi.org/10.33919/ansd.22.7.6

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